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Chelsea's pressure grew and Liverpool were down a star player when Mohamed Salah hobbled off with a groin injury after 33 minutes, leaving him in doubt for the Champions League final against Real Madrid on May 28.
Marcos Alonso then should have put the Blues ahead after being put through by Pulisic, but the Spaniard's first touch let him down, allowing Alisson enough time to put pressure on his close-range shot.
FA CUP FINAL 2021/22 - Saturday May 14 2022 Chelsea - 0 Liverpool - 0 Liverpool win 6-5 on penalties Wembley Stadium, London Attendance: 84,897
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The quadruple dream remains alive for Liverpool, with the Champions League final against Real Madrid on May 28 and the title race still alive, while Chelsea will finish the season without a trophy.
With just a minute played in the second-half, Alonso sprayed a shot wide before Pulisic forced a great save from Alisson.
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