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In the league path, Rangers is on the brink of reaching the playoff round after a 3-0 victory over Viktoria Plzen in its third qualifying round first leg.
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The Belgian side currently holds a 1-0 aggregate lead, as it aims to secure its place in the final qualifying round.
The second league path playoff round tie will be contested between Nice/Benfica and Feyenoord/Fenerbache.
The Portuguese team holds a 2-0 aggregate lead against its Ligue 1 rival, while Arne Slot's former club has a 2-1 advantage over Jose Mourinho's squad.
Meanwhile, the champions path will determine the final five places, with Celtic awaiting one of the third qualifying round winners.
Bodo/Glimt and Sturm Graz have already secured their spots in the playoff round, guaranteeing that one of them will join Liverpool in this season's league phase draw.
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Belgrade will face the victors of Dynamo Kyiv and Pafos, with the Cypriot side currently leading 1-0 on aggregate.
In other news, the final champions path playoff round tie will be contested between Ludogorets Razgrad/Ferencvaros and Shkendija/Qarabag.
The Reds will be drawn against two teams from each pot, with four matches set to be played at Anfield and four on the road.
Champions League league phase already-qualified sides
Pot 1
Paris Saint-Germain Real Madrid Man City Bayern Munich Liverpool Inter Milan Chelsea Borussia Dortmund Barcelona
Pot 2
Arsenal Bayer Leverkusen Atletico Madrid Atalanta Villarreal Juventus Eintracht Frankfurt
Pot 2 or 3
Tottenham Hotspur PSV Eindhoven
Pot 3
Ajax Napoli Sporting CP Olympiacos Slavia Prague Marseille
Pot 3 or 4
Monaco Galatasaray
Pot 4
Union Saint-Gilloise Athletic Bilbao Newcastle United Champions League playoff round
Champions path
Ludogorets Razgrad/Ferencvaros (0-0) vs
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